In order to have precipitation the solution should be...
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A solution must be saturated to be in equilibrium with the solid. ... A supersaturated solution is not at equilibrium, and no solid can ordinarily be present in such a solution. If some of the solid is added, the excess ions precipitate out and until solubility equilibrium is achieved.
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A solution must be saturated to be in equilibrium with the solid.A supersaturated solution is not at equilibrium,and no solid can ordinarily be present in such a solution.If some of the solid is added,the excess ions precipitated out and until solubility equilibrium is achieved
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