In solid state PCl5 is a
a) covalent solid
b) octahedral structure
c) ionic solid with [PCl6]
+ octahedral and [PCl4]
– tetrahedral
d) ionic solid with [PCl4]
+ tetrahedral and [PCl6]
– octahedral
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Answer:
in solid state PCL5 is a solid state
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The extra energy gained by the lattice energy more than compensates for the energy needed to transfer a chloride ion from one PCl5 molecule to another. Thus, PCl5 exists as an ionic solid.
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