in the case of nitrogen all oxidation state from +1 to +4 tends to Disproportionate in acid solution
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In case of Nitrogen, its oxidation number varies from -3 to +5. If Nitrogen has any oxidation number out of +1 to +4 in any compound then it has possibility to increases its oxidation upto +5 and also can decrease upto -3. Hence, all oxidation from +1 to +4 of Nitrogen tend to disproportionate.
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