In the chemical reactions :
the compounds A and B respectively are :
(a) benzene diazonium chloride and benzonitrile
(b) nitrobenzene and chlorobenzene
(c) phenol and bromobenzene
(d) fluorobenzene and phenol
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Answer:
Where are your given reactions
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The compounds A and B respectively are benzene diazonium chloride and benzonitrile.
Option (A) is correct.
Explanation:
The reaction is:
Aniline + NaNO2/ HCl/278 K--->Benzene dizonium chloride ---> Benzonitrile
- In this reaction, aniline is diazotized to obtain benzene diazonium chloride (compound A)
- Aniline is heated in the presence of NaNO2 and HCl. The temperature of the reaction is 278 K.
- In the forst step benzene diazonium chloride is obtained which is further heated in the presence of CuCN to obtain benzonitrile.
- The diazonium group of benzene diazonium chloride is then replaced with cyano group by sandmeyer reaction.
Thus, the compounds A and B respectively are benzene diazonium chloride and benzonitrile.
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