In the confirmatory test of sulphate radical with barium chloride solution, Conc.HCl should not be added. Why?
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Answer:
Here the salt solution E is Na
2
SO
4
. When BaCl
2
solution is added to Na
2
SO
4
, white precipitates of BaSO
4
are formed.
This white precipitate formed are insoluble in dil. HCl. This test is used for the identification of sulphate (SO
4
2−
) radical.
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