Question

In the Electrolytic solution between two electrodes of a battery why positive and negative charges won't attract each other and forced to move towards cathode and anode?​

Answer 1

Answer:

In a galvanic (voltaic) cell, the anode is considered negative and the cathode is considered positive. This seems reasonable as the anode is the source of electrons and cathode is where the electrons flow.

However, in an electrolytic cell, the anode is taken to be positive while the cathode is now negative. However, the reaction is still similar, whereby electrons from the anode flow to the positive terminal of the battery, and electrons from the battery flow to the cathode.

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