In the reaction, 2na2s2o3+ i2--------> na2s4o6+ 2nai, the equivalent mass of na2s2o3(mol. mass = m) is
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In the reaction, 2na2s2o3+ i2--------> na2s4o6+ 2nai, the equivalent mass of na2s2o3(mol. mass = m) is
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Explanation:
2Na₂S₂O₃ + I₂ → Na₂S₄O₆ 2NaI
oxidation of S in S₂O₃⁻² = 2
oxidation number of S in S₄O₆⁻² = 5/2
again, 2S₂O₃⁻² → S₄O₆⁻²
for 2 moles of S₂O₃⁻²
change in oxidation number= 4x5/2 - 2x2x2
= 2
for 1 mole it'll be = 2/2 = 1
∴ equivalent mass of Na₂S₂O₃
= molar mass / change in oxi. no. = 158/1 = 158
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