In the reaction
ROH+HX->RX + 20
1) 2°>1°<3°
2) 3°>2°>19
3) 2°<1°<3°
4) 1°>2°>3
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Explanation:
The reaction R−OH+HX→RX+H
2
O is a nucleophilic substitution reaction where the reactivity of R−OH will depend upon the stability of carbocation that is formed during the reaction via S
N
1 mechanism.
Tertiary carbocations are more stable due to + Inductive effect of alkyl groups then is secondary and least stable is primary carbocation.
The reactivity of alcohols will follow the order
Tertiary alcohol > secondary alcohol > primary alcohol
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