In Victor Meyer’s experiment, 0.23g of a volatile solute displaced air which measures 112 ml at NTP. Calculate the vapour density and molecular weight of the substance.
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Volume occupied by solute at NTP = Volume of air displaced at NTP = 112 ml
For volatile solute PV = w / M RT
at NTP, P = 1 atm, T = 273 K
1 × 112/ 1000 = 0.23 / m × 0.0821 × 273
m = 46.02 and V.D. = 23.01
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