inductive effect with carboxylic group
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Carboxylic acids
In acids, the electron-releasing inductive effect of the alkyl group increases the electron density on oxygen and thus hinders the breaking of the O-H bond, which consequently reduces the ionization. ... In benzoic acid, the carbon atoms which are present in the ring are sp2 hybridised.
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As an acid becomes stronger, the numerical value of its pKa drops. In acids, the electron-releasing inductive effect of the alkyl group increases the electron density on oxygen and thus hinders the breaking of the O-H bond, which consequently reduces the ionization.
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