Chemistry, asked by royalaluminiumi515, 8 months ago

Is ClF3 Polar Or NonPolar Molecule

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Answered by Anonymous
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Chlorine trifluoride is an interhalogen compound with the formula ClF3. This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). The compound is primarily of interest as a component in rocket fuels, in plasmaless cleaning and etching operations in the semiconductor industry, in nuclear reactor fuel processing,and other industrial operations.

It was first reported in 1930 by Ruff and Krug who prepared it by fluorination of chlorine; this also produced ClF and the mixture was separated by distillation.

3 F2 + Cl2 → 2 ClF3

The molecular geometry of ClF3 is approximately T-shaped, with one short bond (1.598 Å) and two long bonds (1.698 Å).[14] This structure agrees with the prediction of VSEPR theory, which predicts lone pairs of electrons as occupying two equatorial positions of a hypothetic trigonal bipyramid. The elongated Cl-F axial bonds are consistent with hypervalent bonding.

Pure ClF3 is stable to 180 °C in quartz vessels; above this temperature it decomposes by a free radical mechanism to its constituent elements.

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