Is it possible for molecules having more than 8 electrons in their valence orbit still they are stable
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No a stable molecule neither gains electrons nor lose them.
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Yes. While having an octet of valence electrons creates an exceptionally deep energy minimum for most atoms, it is only a minimum, not a fundamental requirement. If there are sufficiently strong compensating energy factors, even atoms that strongly prefer octets can form stable compounds with more (or less) than the 8 valence shell electrons.
However, the same bonding mechanisms that enable formation of greater-than-8 valence shells also enable alternative structural interpretions of such shells, depending mostly on whether such bonds are interpreted as ionic or covalent.
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