It happens :)
1)when heating pcl⁵
2)when the white phosphorous is heated is an inert atmosphere of Co²
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1. It has three equatorial and two axial bonds. The equatorial bonds are stronger than the axial ones. Therefore, when PCl5 is heated strongly, it decomposes to form PCl3.
2.White phosphorus reacts with NaOH to form phosphine.
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