(iv) Sigmatropic rearrangements involve shifting of
bonds.
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Molecular rearrangements in which a σ-bonded atom or group, flanked by one or more π-electron systems, shifts to a new location with a corresponding reorganization of the π-bonds are called sigmatropic reactions. ... The most common atom to undergo sigmatropic shifts is hydrogen or one of its isotopes
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Answer:Molecular rearrangements in which a σ-bonded atom or group, flanked by one or more π-electron systems, shifts to a new location with a corresponding reorganization of the π-bonds are called sigmatropic reactions. ... The most common atom to undergo sigmatropic shifts is hydrogen or one of its isotopes.
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