Jexplain Hofmary booranide degradation with ane example
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Hofmann rearrangement
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The Hofmann rearrangement (Hofmann degradation) is the organic reaction of a primary amide to a primary amine with one fewer carbon atom.[1][2][3] The reaction involves oxidation of the nitrogen followed by rearrangement of the carbonyl and nitrogen to give an isocyanate intermediate. The reaction can form a wide range of products, including alkyl and aryl amines.
Hofmann rearrangement
Named after
August Wilhelm von Hofmann
Reaction type
Rearrangement reaction
Identifiers
RSC ontology ID
RXNO:0000410
The Hofmann rearrangement
The reaction is named after its discoverer, August Wilhelm von Hofmann, and should not be confused with the Hofmann elimination, another name reaction for which he is eponymous.
Mechanism
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Last edited 4 months ago by DMacks
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