kinetics of polymerization
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The polymerization of alkenes occurs in a very different way than monomers that undergo condensation reactions. Whether it occurs through an anionic, cationic, or radical mechanism, polymerization of alkenes involves a chain reaction. Chain reactions are classically illustrated by radical chemistry, so we will look at a treatment of radical chain polymerization to see some of the factors that influence polymerization rates.
A typical radical polymerization starts with the thermal decomposition of a radical initiator to provide two radicals. The rate of decomposition depends only on the decomposition rate constant and the concentration of the initiator.
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Ziff‐ cited by 306
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