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1. The radius of the nucleus is: R = 1.25 × 10⁻¹³
Now, we have assumed here that The nucleus is a sphere, so, the volume of the sphere is: πr³
Now, radius of the atom formula = radius of nucleus x cube root of mass number of the atom
= 1.25 × 10⁻¹³ x = 1.25 x 10⁻¹³ x 4 = 5 x 10⁻¹³
now, radius of atom = 1 Å = 10⁻¹⁰ m = 10⁻⁸ cm (multiply by 100, since all the values are given in cm)
Volume occupied by the nucleus in the atom is:
=
(
π get cancelled both in the numerator and denominator)
= = 125 x 10⁻¹⁵ cm = 1.25 x 10⁻¹³ cm
2. The value of n will be only natural numbers (not even 0)
Now, the formula of the excited state of the hydrogen atom is:
If n=1, then, = -13.6eV
if n=2, then, = -3.4eV
so, the possible value is only option (a) -3.4 eV