Let hydrolysis constant (Kh) of NH_4^+ be y. Then equilibrium constant (Ka) for conjugate acid of NH3 at 25°C is: (a) 1/y×10^(-14) (b) 10^(-14) (c) y (d) y×10^(-14)
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11th
Chemistry
Equilibrium
Hydrolysis of Salts and the pH of their Solutions
The dissociation constant o...
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Asked on December 30, 2019 by
Eswar Vishwavani
The dissociation constant of NH
4
OH is 1.8×10
−5
. The hydrolysis constant of NH
4
+
ions at 25
0
C would be:
MEDIUM
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ANSWER
The relationship betwen the hydrolysis constant of the salt ammonium chloride and the base dissociation constant of ammonia is as given below:
K
h
=
K
b
K
w
Substituting values in the above expression, we get:
K
h
=
1.8×10
−5
1×10
−14
=5.556×10
−10
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