limitations of first law of thermodynamics
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Limitations of First Law of Thermodynamics. First law does not provide a clear idea about the direction of absorption or evolution of heat. The informations provided by the first law of thermodynamics are not enough to predict the spontaneity or feasibility of a process.
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First law of thermodynamics states that the relation between different energies for a process. But doesn't tell about either a process is spontaneous or feasible or not means reaction is possible by itself or not...
This spontaneous nature is explained by second law of thermodynamics...
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