Limitations of slaters rule
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Limitations of Slater's rules .
1. According to Slater's rules, the outer shell electrons do not shield the inner electrons . This may not be true. ... According to the Slater's rules, the s,p,d and f electrons of the same shell screen the higher shell electrons to the same extent.
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According to Slater's rules, the outer shell electrons do not shield the inner electrons . This may not be true. For example, even the outer S electrons penetrate quite to the nucleus and would thus exercise a shielding effect.
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