Question

List the empirical rules that govern the formation of substitutional solid solution.

Answer 1

Answer:

Substitutional solid solution rules

A metal with lower valency is more likely to dissolve in a metal of higher valency. The solute and solvent should have similar electronegativity. If the electronegativity difference is too great, the metals tend to form intermetallic compounds instead of solid solutions.

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Answer 2

Substitutional solid solution rules

• The atomic radius of the solute and solvent atoms must differ by no more than 15%:
• The atomic radius of the solute and solvent atoms must differ by no more than 15%:The crystal structures of solute and solvent must be similar.
• The atomic radius of the solute and solvent atoms must differ by no more than 15%:The crystal structures of solute and solvent must be similar.Complete solubility occurs when the solvent and solute have the same valency. ...
• The atomic radius of the solute and solvent atoms must differ by no more than 15%:The crystal structures of solute and solvent must be similar.Complete solubility occurs when the solvent and solute have the same valency. ...The solute and solvent should have similar electronegativity.

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