LUI
4.23
The rate constant for the decomposition of hydrocarbons is 2.418 x 10 %
1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the
value of pre-exponential factor.
Consider a certain
ith k= 2.0 x 10-2g-1. Calculate
4.24
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Answer:
By using arrhenius equation,
⟹logk=
2.303 RT
−E
a
+logA
We get
⟹logA=log(2.418×10
−5
)+
2.303×8.314×546
179900
⟹(log2.418)−5+15.7082)
⟹0.3834−5+17.209=12.6
∴logA=(12.6)=3.9×10
12
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