markonicove rule in chemistry
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HeYa......
When addition reaction takes place across unsymmaletric multiple bond, the negative part of addendum goes to that carbon atom which contain least number of hydrogen atom. In presence of peroxide antimarkownikov's rule takes place. It is called peroxide effect.
(a) CH3-CH=CH2 + HBr --> CH3-CHBr-CH3
2-Bromopropane
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Markovnikov's rule is an empirical rule used to predict regioselectivity of electrophilic addition reactions of alkenes and alkynes. ... To afford the observed product, the net reaction is addition of the hydrogen atom in HBr to the doubly bonded carbon atom in the alkene, bearing the greater number of hydrogen atoms.
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