Markovnikov rule explain it
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Markonikoff's rule: When an unsymmetrical reagent is added to an unsymmetrical alkene, the negative part of the reagent is attached to the unsaturated C atom having less number of hydrogen atoms.
Thus, when HBr is added to propene, isopropyl bromide is obtained as major product.
CH
3
−CH=CH
2
+HBr→CH
3
−
CH
∣
Br
−CH
3
Thus, bromide ion is added to middle carbon atom (having less number of H atoms) and proton is attached to terminal C atom.
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