Mention the difference between calcination and roasting How these
processes are used in the extraction of zinc ? Explain with the help of
chemical equations. After these processes, is reduction necessary to obtain
zinc ? Why?
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Ë Carbonate ores are converted into oxides by heating strongly in limited air. This process is known as calcination. 2 1
Ë Sulphide ores are converted into oxides by heating strongly in the presence of excess of air. This process is known as roasting. 2 1 Ë When ZnCO3 undergoes calcination ZnO is formed. ZnCO3 ( s ) ⎯ ⎯ ⎯→⎯ heat ZnO ( s ) + CO2 ( g ). 1
Ë When ZnS undergoes roasting, ZnO is formed. 2 ZnS ( s ) + 3O2 ( g ) ⎯ ⎯ ⎯→⎯ heat 2 ZnO ( s ) + 2 SO2 ( g ). 1 Ë After these processes reduction is necessary. 2 1
Ë Because zinc oxide is then reduced to zinc using suitable reducing agent. 2
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