mention the necessary conditions for hybridization and explain shape of pcl5 molecule based on hybridization also explain in this molecule why all p-cl bond-lengths are not identical.
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Answer:
Explanation:
P has ground state valence shell electronic configuration 3s
2
3p3 and the first excited state valence shell electronic configuration is 3s
1
3p
3
3d
1
.
P undergoes sp
3
d hybridization and has trigonal bipyramidal geometry.
Axial Cl atoms experience higher electron repulsion than equatorial chlorine atoms.
Hence, the axial bonds are longer as compared to equatorial bonds.
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