MODERN COLLEGE CHEMISTRY (SEM-11)
18
C2HCl + CoHo AlCl3, CH3CH2CH3 + HCI
Ethyl chloride Benzene
Ethyl benzene
13. Action with active methylene compounds. We get alkyl substituted esters.
C2H5--Br + [CH3CO, CHCOOC2H5)Nat
CH3 COCH(C2H5) COOC2H5 NaBr
Ethylacetoacetic ester
Sodioacetoacetic ester
Problem. ROH reacts with NaBr in presence of H.SO, to give RBr. Why is H2SO, required? What is the
mechanism of the reaction ?
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