monomers containing electropositive groups like CH3 ,C6H5 at one of the carbon atoms connected by the double bond follow cationic mechanism in presence of.
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Heterocyclic monomers that are cationically polymerized are lactones, lactams and cyclic amines. Upon addition of an initiator, cyclic monomers go on to form linear polymers. The reactivity of heterocyclic monomers depends on their ring strain.
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