N heptane 2 methyl hexane 3 methyl hexane 2,2 di methyl pentane 3,3 di methyl pentane 2,4 di methyl pentane 3 ethyl pentane 2,2,3 tri methyl butane 2,3 di methyl pentane
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Boiling point ∝ Molecular weight
Boiling point ∝ Branching.
3,3-dimethylpentane, 2-methylhexane, and n-heptane all have same molecular weight but the order of branching is
3,3-dimethylpentane > 2-methylhexane > n-heptane
So, the order of boiling point is
3,3-dimethylpentane > 2-methylhexane > n-pentane
Hence, hydrocarbon with the highest boiling point is 3,3-dimethylpentane and that with the lowest boiling point is n-heptane.
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