Na2co3 can be manufactured by solvay process but k2co3 cannot be prepared because
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The Solvay process or ammonia-soda process is the major industrial process for the production of sodium carbonate. The ammonia-soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. The ingredients for this are readily available and inexpensive: salt brine and limestone.
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