NaCI has higher melting point as compared to nephthalane
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Also, magnesium is more electronegative as compared to sodium. These factors combine to result in a higher force of attraction in sodium chloride as compared to magnesium chloride and hence a higher melting point for the former.
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NaCl is a ionic compound having Face Centered Cubic structure, its melting point higher where as Naphthalene is a aromatic covalent compound, its melting point is low.
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