Chemistry, asked by junaid6067, 1 year ago

Name the non stoichiometric point defect responsible for colour in alkali metal halides

Answers

Answered by khiladi4
17
metal excess defect which is responsible for occurrence of f -centre
Answered by hotelcalifornia
3

Non-stoichiometric defect responsible for color in alkali metal halide is metal excess (anion -vacancy) defect.

Explanation:

  • Metal excess defect is accountable for mainly colour in 'alkyl halides'.
  • For example, When crystals of NaCl are heated in an atmosphere of Na vapor, the Na atoms are accumulated on the surface of the crystals.
  • And Cl^- ions 'diffuse' to the 'surface' of the crystals to 'combine' with Na to form NaCl.
  • This occurs by 'loss of electrons' by Na atoms to createNa^+.
  • These liberate electrons distribute into the crystals and utilise anionic sites and imparts colour to crystal.

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