name the reagent used in the reaction ,"oxidation of primary alcohol to carboxylic acid."
Answers
Answered by
1
The reaction starts with the formation of an organic nitric acid ester
(as these compounds are dangerously unstable, as Uncle Al already
pointed out, I would not recommend to use nitric acid for this
oxidation). The negatively charged nitrate oxygen abstracts an alpha
proton from the alkyl group, and HNO2
is eliminated, yielding the aldehyde. Nucleophilic attack of nitrate on
the carbonyl group and subsequent elimination of another equivalent HNO2 finally yields the carboxylate.
Similar questions