Question

Ncl3 gets radially hydrolysed while nf3 does not why

Answer 1

Answer:

In NF3 neither N nor F has vacant orbitals but Cl in NCl3 has vacant d orbitals to accommodate electrons and gets hydrolysed.

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Answer 2

Answer:In NF3 neither N nor F has vacant orbitals but Cl in NCl3 has vacant d orbitals to accommodate electrons and gets hydrolysed.

It is similar to ccl4 and sicl4

NF3 is an exothermic reaction where as NCl3 is an endothermic reaction