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Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for determining the age of an object containing organic material by using the properties of radiocarbon (14
C), a radioactive isotope of carbon.
The method was developed by Willard Libby in the late 1940s and soon became a standard tool for archaeologists. Libby received the Nobel Prize for his work in 1960. The radiocarbon dating method is based on the fact that radiocarbon is constantly being created in the atmosphere by the interaction of cosmic rays with atmospheric nitrogen. The resulting radiocarbon combines with atmospheric oxygen to form radioactive carbon dioxide, which is incorporated into plants by photosynthesis; animals then acquire 14
C by eating the plants. When the animal or plant dies, it stops exchanging carbon with its environment, and from that point onwards the amount of 14
C it contains begins to decrease as the 14
C undergoes radioactive decay. Measuring the amount of 14
C in a sample from a dead plant or animal such as a piece of wood or a fragment of bone provides information that can be used to calculate when the animal or plant died. The older a sample is, the less 14
C there is to be detected, and because the half-life of 14
C (the period of time after which half of a given sample will have decayed) is about 5,730 years, the oldest dates that can be reliably measured by radiocarbon dating are around 50,000 years ago, although special preparation methods occasionally permit dating of older samples
Radiocarbon oxidizes (that is, it combines with oxygen) and enters the biosphere through natural processes like breathing and eating. Plants and animals naturally incorporate both the abundant C-12 isotope and the much rarer radiocarbon isotope into their tissues in about the same proportions as the two occur in the atmosphere during their lifetimes. When a creature dies, it ceases to consume more radiocarbon while the C-14 already in its body continues to decay back into nitrogen. So, if we find the remains of a dead creature whose C-12 to C-14 ratio is half of what it's supposed to be (that is, one C-14 atom for every two trillion C-12 atoms instead of one in every trillion) we can assume the creature has been dead for about 5,730 years (since half of the radiocarbon is missing, it takes about 5,730 years for half of it to decay back into nitrogen). If the ratio is a quarter of what it should be (one in every four trillion) we can assume the creature has been dead for 11,460 year (two half-lives). After about 10 half-lives, the amount of radiocarbon left becomes too miniscule to measure and so this technique isn't useful for dating specimens which died more than 60,000 years ago. Another limitation is that this technique can only be applied to organic material such as bone, flesh, or wood. It can't be used to date rocks directly.
Carbon Dating - The Premise
Carbon dating is a dating technique predicated upon three things:
The rate at which the unstable radioactive C-14 isotope decays into the stable non-radioactive N-14 isotope,
The ratio of C-12 to C-14 found in a given specimen,
And the ratio C-12 to C-14 found in the atmosphere at the time of the specimen's death.
Carbon Dating - The Controversy
Carbon dating is controversial for a couple of reasons. First of all, it's predicated upon a set of questionable assumptions. We have to assume, for example, that the rate of decay (that is, a 5,730 year half-life) has remained constant throughout the unobservable past. However, there is strong evidence which suggests that radioactive decay may have been greatly accelerated in the unobservable past.1 We must also assume that the ratio of C-12 to C-14 in the atmosphere has remained constant throughout the unobservable past (so we can know what the ratio was at the time of the specimen's death). And yet we know that "radiocarbon is forming 28-37% faster than it is decaying,"2 which means it hasn't yet reached equilibrium, which means the ratio is higher today than it was in the unobservable past. We also know that the ratio decreased during the industrial revolution due to the dramatic increase of CO2 produced by factories. This man-made fluctuation wasn't a natural occurrence, but it demonstrates the fact that fluctuation is possible and that a period of natural upheaval upon the earth could greatly affect the ratio. Volcanoes spew out CO2 which could just as effectively decrease the ratio. Specimens which lived and died during a period of intense volcanism wou