Negative deviation from ideal behaviour is due to the fact that
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Deviations from ideal behaviour are observed particularly at high pressures or low temperatures. When Z < 1, it is a negative deviation. ... When Z > 1, it is a positive deviation. It shows that the gas is less compressible than expected from ideal behaviour.
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Deviations from ideal behaviour are observed particularly at high pressures or low temperatures. When Z < 1, it is a negative deviation. ... When Z > 1, it is a positive deviation. It shows that the gas is less compressible than expected from ideal behaviour.
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