No of pi and sigma bond in structure of preocxyisulphuric acid
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Sigma (σ) bond : When a bond is formed between two atoms by the overlap of their atomic orbitals along the internuclear axis (i.e. end to end or head on overlap) then the bond formed are called as sigma bond.
In simple meanings the orbitals should be placed so that they lie in internuclear axis.
For ex: s-s overlap or s-pz overlap (as pz lie along the internuclear axis) or pz-pzoverlaps

Pi (π) bond: It is a bond formed by lateral (i.e. sideways) overlap of two p orbitals , i.e the overlapping of p-orbitals in a direction which is right angles to the internuclear axis.
Ex:

Sigma (σ) bond : When a bond is formed between two atoms by the overlap of their atomic orbitals along the internuclear axis (i.e. end to end or head on overlap) then the bond formed are called as sigma bond.
In simple meanings the orbitals should be placed so that they lie in internuclear axis.
For ex: s-s overlap or s-pz overlap (as pz lie along the internuclear axis) or pz-pzoverlaps

Pi (π) bond: It is a bond formed by lateral (i.e. sideways) overlap of two p orbitals , i.e the overlapping of p-orbitals in a direction which is right angles to the internuclear axis.
Ex:

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