Note on alternant and non alternant hydrocarbons
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Non-alternant hydrocarbons: These hydrocarbons have invariably feature at least one ring constructed with an odd number of carbon atoms.
Alternant hydrocarbon : It is any conjugated hydrocarbon system which does not possess an odd-membered ring.
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One of the most important distinctions made at the Hückel level is that between alternant (e.g. 1) and non-alternant hydrocarbons (e.g. 2). Non-alternant hydrocarbons invariably feature at least one ring constructed with an odd number of carbon atoms, whereas alternant hydrocarbons have no such rings2-4.
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