Number of moles of electrons involved in each of the following 4H+ + o2— 2H2o and H2o + 2H +—2H2o
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The reduction of water leads to the formation of hydrogen and oxygen. Where hydrogen is generated, the half cell reaction is simple:
At the cathode (reduction) -
2 H+(aq) + 2e− → H2(g) E = 0.00 V
At the anode (oxidation)
2 H2O(l) → O2(g) + 4 H+(aq) + 4e− E = -1.23 V
recall though, these reactions in water is pH dependent and will vary with the material used to achieve water splitting (i.e. overpotentials to actually observe reactivity) - if its just pure water this is essentially what is occurring.
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