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Explain the meaning of - I and + I effect. Arrange the following in order
decreasing - I effect.
-CN, -NO2, -COOH, N(Me)4, -Ph
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Answer:
-N(Me)4 > -NO2 > -CN > -COOH > -ph
Explanation:
-i effect order
- NF3 > N(R)3 > NH3 > NO2 > CN > -CHO > -C=O >-COOH > F > cl> Br > I > -OR >-OH
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INDUCTIVE EFFECT - DEFINITION
When a covalent bond is formed between atoms of different electronegativity , the electron density is more towards the more electronegative atoms of the bond,such a shift in electron density is called as inductive effect.
Example : CH3
CH 2
Cl in this molecule chlorine is a electronegative atom always shift electron pair towards it self.
-CN<-NO2< -COOH<N(Me)4 <-Ph
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