on the electrolysis of acidified water the mass of oxygen liberated at the anode by passing 9650 Faraday electricity is
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we have to find the mass of oxygen of acidified water at anode by passing 9650 Faraday.
solution : electrolysis of water is given by,
2H₂O ⇄ 2H₂ + O₂
at anode,
4OH⁻ ⇆ 2H₂O + O₂ + 4e⁻
here you can see that one mole of oxygen gas is liberated when 4 moles of electrons are released.
we know, one mole of electrons liberates 96500c charge.
so, 9650 C charge is equivalent to 0.1 mol of electrons.
now, no of moles of oxygen liberated at anode = 0.1/4 = 0.025 mol
mass of oxygen = moles × molecular mass of oxygen gas
= 0.025 × 32 = 0.8 g
Therefore mass of liberated oxygen at anode is 0.8g
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