One-step construction of molecular complexity by tert-butyl nitrite (tbn)-initiated cascade ,-sp3 c-h bond difunctionalization and c-n bond cleavage
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TBN-initiated cascade multifunctionalization of inert C-H and C-N bonds in N-arylazacycles has been realized under transition-metal free conditions, in which the synthetically useful oxime, N-NO and aldehyde functional groups were constructed in only one synthetic step.
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