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a)
1. cannizzaro reaction
aldehydes which do not have an Alpha hydrogen atom undergoes self oxidation and reduction reaction on heating with con. alkali.
see the reaction in first attachment
2. decarboxylation
Decarboxylation : the reaction in which carboxylic acids lose carbon dioxide to form hydrocarbons when their sodium salts are heated with soda-lime.
alkali metal salts of carboxylic acid also undergo decarboxylation electrolysis of their aqua solution. This reaction is known as Kolbe's electrolysis.
see the reactions in attachment second
b) see all the reactions in third attachment
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