Question

Ortho-Nitrophenol is less soluble in water than p- and m- Nitrophenols because :
(a) o-Nitrophenol is more volatile than those of m- and pisomers.
(b) o-Nitrophenol shows intramolecular H-bonding
(c) o-Nitrophenol shows intermolecular H-bonding
(d) Melting point of o-Nitrophenol is lower than those of m- and p-isomers.

Answer 1

ans (b) intramolecular h bonding

so no scope of intermolecular h bonding