Other than the effort to generate negetive radicals why can't they be used instead of electrons ?
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There are three factors Affect Free-Radical Stability :
1. Stability Of Free Radicals Increases In The Order Methyl < Primary < Secondary < Tertiary
stability-of-free-radicals-increases-in-the-order-methyl-primary-secondary-tertiary
2. Free Radicals Are Stabilized by Delocalization (“Resonance”)
3. The Geometry of Free Radicals Is That Of A “Shallow Pyramid”, Which Allows For Overlap Of The Half-Filled p-Orbital With Adjacent Pi Bonds
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