out of n-pentane and neopentane which has more vander Waal forces and why?
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Notice that n-pentane is roughly sausage-shaped, whereas neopentane is a spherical ball. ... In contrast, in a liquid the long n-pentane sausages lie in closer contact with one another than the neopentane spheres do, so intermolecular van der Waals forces are stronger, and the boiling point of n-pentane is highest of all.
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