Out of o- and p-dibromobenzene which one has higher melting
point and w
Haloarenes are less reactive than haloalkane and haloalkene.
Explain.
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Explanation
(A)There is perfect symmetry in p-dibromobenzene which can fit into
Crystal lattices very well.
where there is less symmetry in o-dibromobenzene .
(B) haloarenes are less reactive than haloarenes due to the following reasons
(a) due to resonance, the C-Cl bond
acquires partial double character .
(b) C of C-X bond in haloarene is sp2 - hybridised whereas C of C-X bond is sp3 - hybridised.
(c) instability of phenyl cation
(d) it is less likely for the incoming nucleophile to reach electron rich arenes.
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