Oxygen cannot exhibit +4,+6 oxidation states where as sulphur can
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Sulfur has 3d orbitals available; Oxygen does not. The 3d orbitals in sulfur allow for more unpaired electrons to be established in the excited state.
4 unpaired electrons would allow +4 oxidation state.
If all of the valence electrons become unpaired, that giving a +6 oxidation state.
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Chemical Properties of Sulphur. Sulphur exhibits oxidation numbers of -2, 0, +2, +4 and +6. Oxidation number -2 is seen in the sulphide ion, S--, and a typical compound is H2S, hydrogen sulphide or hydrosulphuric acid.
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