p nitroaniline or benzylamine which is more basic?
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Answer:
benzylamine is more basic
Explanation:
in benzylamine, the lone pair of nitrogen is in conjugation with the aromatic system (benzene ring). So, it is delocalized and is not freely available for donation. So, nitroaniline is less basic.
In benzyl amine the lone pair of nitrogen is not in conjugation with the benzene ring and it is free for donation to an electrophile.
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