प्रश्न-4
प्राथमिक एमीन की तुलना में द्वितीयक एमीन अधिक क्षारकीय होते हैं, क्यों?
Why secondary amines are more basic than the
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Secondary Amines have basicity higher than the Primary Amines
Explanation:
The order of basicity of amines are:
Secondary Primary Tertiary
- The electron donating groups increase the basicity of an molecule. There are two electron donating groups present in secondary amines.
- Also, there's not an excessive amount of steric hindrance, which decreases basicity.
- They produce strong basic anions called as amides when deprotonated.
- The alkyl groups donate the electrons to the strong electronegative nitrogen.
- The electron density is created due to the inductive effect than the nitrogen of ammonia.
- Correspondingly, the basicity of the amines are of these order.
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